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Question -

Discuss the principle and method of softening of hard water by synthetic ion-exchange resins.



Answer -

Cation exchange resinshave large organic molecule with S03H group which are insoluble in water. Ion exchangeresin (RS03H) is changed to RNa on treatment with NaCl. Theresin exchange Na+ ions with Ca2+ and Mg2+ ions present in hard water and make it soft.
2RNa(s) + M2+(aq) ——> R2M(s) + 2Na+(aq)
where, M = Mg, Ca.
The resins can be regenerated by adding aqueousNaCl solution.

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