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Question -

Why is the extraction of copperfrom pyrites more difficult than that from its oxide orethrough reduction?



Answer -

The Gibbs free energy of formation (ΔfG)of Cu2S is less thanthat of and. Therefore, H2 and C cannot reduceCu2S to Cu.
Onthe other hand, the Gibbs free energy of formation of is greater than that of

Hence, C can reduce Cu2O to Cu.

Hence, the extraction of copperfrom its pyrite ore is difficult than from its oxide ore through reduction.

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