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Question -

The rate constant for the decomposition of N_2O_5 at various temperatures is given below:



Answer -


T/°C

0

20

40

60

80

0.0787

1.70

25.7

178

2140

Draw a graph between ln and1/and calculate the values of and Ea.

Predictthe rate constant at 30º and 50ºC.

Answer

From the given data, we obtain

T/°C

0

20

40

60

80

T/K

273

293

313

333

353

3.66×10−3

3.41×10−3

3.19×10−3

3.0×10−3

2.83 ×10−3

0.0787

1.70

25.7

178

2140

ln k

−7.147

− 4.075

−1.359

−0.577

3.063

                                        
When 
Again, when 

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