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Question -

The following results havebeen obtained during the kinetic studies of the reaction:

2A + B → C + D



Answer -

Experiment

A/ mol L−1

B/ mol L−1

Initial rate of formation of D/mol L−1 min−1

I

0.1

0.1

6.0 × 10−3

II

0.3

0.2

7.2 × 10−2

III

0.3

0.4

2.88 × 10−1

IV

0.4

0.1

2.40 × 10−2

Determine the rate law and therate constant for the reaction.

Answer

Let the order of the reactionwith respect to A be x and with respect to B be y.

Therefore, rate of the reactionis given by,

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