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Question -

For the decomposition ofazoisopropane to hexane and nitrogen at 543 K, the following data are obtained. 



Answer -

t (sec)

P(mm of Hg)

0

35.0

360

54.0

720

63.0

Calculate the rate constant.

Answer

The decomposition ofazoisopropane to hexane and nitrogen at 543 K is represented by the followingequation.

After time, t, total pressure,

= 2P0 − Pt

For a first order reaction,

= 2.21 × 10−3 s−1

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