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Question -

Ferric oxidecrystallises in a hexagonal close-packed array of oxide ions with two out ofevery three octahedral holes occupied by ferric ions. Derive the formula of theferric oxide.



Answer -

Let the number of oxide(O2−) ions be x.

So, number of octahedralvoids = x

It is given that two outof every three octahedral holes are occupied by ferric ions.

So, number of ferric (Fe3+) ions
Therefore, ratio of the number of Fe3+ ions to the number of O2− ions,
Fe
3+ : O2−

= 2 : 3

Hence, the formula ofthe ferric oxide is Fe2O3.

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