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Question -

Draw all the isomers (geometrical andoptical) of:




Answer -

(i) [CoCl_2(en)_2]_+

(ii) [Co(NH_3)Cl(en)_2]_2+

(iii) [Co(NH_3)_2Cl_2(en)]_+
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_Answer
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(i) [CoCl2(en)2]Geometricalisomerism

Opticalisomerism Since only cis isomer isoptically active, it shows optical isomerism.

In total, three isomers are possible.

(ii) [Co(NH3)Cl(en)2]2+

Geometrical isomerism

Optical isomerism Since only cis isomer isoptically active, it shows optical isomerism.

(iii) [Co(NH3)2Cl2(en)]+

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