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Question -

Describe the manufacture of H2SO4 bycontact process?



Answer -

Sulphuric acid is manufactured bythe contact process. It involves the following steps:

Step (i):

Sulphur or sulphide ores areburnt in air to form SO2.

Step (ii):

By a reaction with oxygen, SO2 isconverted into SO3 in the presence of V2O5 asa catalyst.

Step (iii):

SO3 produced isabsorbed on H2SO4 to give H2S2O7 (oleum).

This oleum is then diluted toobtain H2SO4 of the desired concentration.

In practice, the plant isoperated at 2 bar (pressure) and 720 K (temperature). The sulphuric acid thusobtained is 96-98% pure.

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