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Question -

Calculate the mass of anon-volatile solute (molar mass 40 g mol−1) which should bedissolved in 114 g octane to reduce its vapour pressure to 80%.



Answer -

Let the vapour pressure of pure octane be

Then, the vapour pressure of the octane afterdissolving the non-volatile solute is

Molar mass of solute, M2 =40 g mol−1

Mass of octane, w1 =114 g

Molar mass of octane, (C8H18), M1 =8 × 12 + 18 × 1

= 114 g mol−1

Applyingthe relation,

Hence, the required mass of thesolute is 8 g.

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