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Question -

Boiling point of water at 750 mmHg is 99.63┬░C. How much sucrose is to be added to 500 g of water such that itboils at 100┬░C.┬аMolal elevation constant for water is 0.52 K kg molтИТ1.



Answer -

Here, elevation of boiling point╬ФTb┬а= (100 + 273) тИТ (99.63 + 273)

= 0.37 K

Mass of water,┬аwl┬а=500 g

Molar mass of sucrose (C12H22O11),┬аM2┬а=11 ├Ч 12 + 22 ├Ч 1 + 11 ├Ч 16

= 342 g molтИТ1

Molal elevation constant,┬аKb┬а=0.52 K kg molтИТ1

We know that:

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