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Question -

Estimate the fraction of molecular volume to the actual volume occupied by oxygen gas at STP. Take the diameter of an oxygen molecule to be 3 Å.



Answer -

Diameter of an oxygen molecule, d = 3 Å

Radius, r = d / 2

r = 3 / 2 = 1.5 Å = 1.5 x 10 -8 cm

Actual volume occupied by 1 mole of oxygen gas at STP = 22400 cm3

Molecular volume of oxygen gas, V = 4 / 3 πr3. N

Where, N is Avogadro’s number = 6.023 x 1023 molecules/mole

Hence,

V = 4 / 3 x 3.14 x (1.5 x 10-8)3 x 6.023 x 1023

We get,

V = 8.51 cm3

Therefore, ratio of the molecular volume to the actual volume ofoxygen = 8.51/ 22400 = 3. 8 x 10-4

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