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Question -

What are the necessary conditions for any system to be aromatic?



Answer -

The necessary conditions for amolecule to be aromatic are:

·        It should have a single cyclic cloudof delocalised n-electrons above and below the plane of the molecule.

·        It should be planar. This is becausecomplete delocalization of n-electrons is possible only if the ring is planarto allow cyclic overlap of p-orbitals.

·        It should contain Huckel number ofelectrons, i.e., (4n + 2) n-electrons where n = 0, 1, 2, 3 etc.
A molecule which does not satisfy any one or more of the above conditions issaid to be non-aromatic.

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