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Question -

The ionization constant of nitrous acid is4.5 × 10–4. Calculate the pH of 0.04 M sodium nitritesolution and also its degree of hydrolysis.



Answer -

NaNO2 is the salt of astrong base (NaOH) and a weak acid (HNO2).

Now, If x moles of the saltundergo hydrolysis, then the concentration of various species present in thesolution will be:

Therefore,degree of hydrolysis

=2.325 × 10–5

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