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Question -

Reaction between N2 and O2 takes place asfollows:

If a mixture of 0.482 mol of N2 and 0.933 mol of O2 is placed in a 10 Lreaction vessel and allowed to form N2O at a temperature forwhich Kc = 2.0 × 10–37, determine thecomposition of equilibrium mixture.



Answer -

Let the concentration of N2O at equilibrium be x.

Thegiven reaction is:

 

Therefore,at equilibrium, in the 10 L vessel:

The value of equilibrium constant i.e., = 2.0 × 10–37 is very small.Therefore, the amount of N2 and O2 reacted is also verysmall. Thus, x can be neglected from the expressions of molarconcentrations of N2 and O2.

Then,

 

Now,

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