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Question -

How do you account for the formation of ethane during chlorination of methane?




Answer -

Chlorination of methane is a free radical reaction which occurs by the following mechanism:

Fromthe above mechanism, it is evident that during propagation step, CH3 free radicals areproduced which may undergo three reactions, i.e., (i) — (iii). In the chaintermination step, the two CH3 freeradicals combine together to form ethane (CH3—CH3)molecule.

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