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Question -

Determine the molecular formula of an oxideof iron in which the mass per cent of iron and oxygen are 69.9 and 30.1respectively. Given that the molar mass of the oxide is 159.69 g mol–1.



Answer -

Mass percent of iron (Fe) = 69.9% (Given)

Masspercent of oxygen (O) = 30.1% (Given)

Number of moles of iron present in the oxide 

= 1.25

Number of moles of oxygenpresent in the oxide 

= 1.88

Ratio ofiron to oxygen in the oxide,

= 1 : 1.5

= 2 : 3

Theempirical formula of the oxide is Fe2O3.

Empirical formula mass of Fe2O3 = [2(55.85) + 3(16.00)] g

Molar mass of Fe2O3 = 159.69 g

Molecular formula of a compound is obtainedby multiplying the empirical formula with n.

Thus, the empirical formula of the givenoxide is Fe2O3 and n is 1.

Hence, the molecular formula of the oxide isFe2O3.

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