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Question -

Consider the following species:

N3–, O2–, F, Na+, Mg2+ and Al3+

(a) What is common in them?

(b) Arrange them in the order of increasingionic radii.

 



Answer -

(a) Each of the given species (ions) has the same numberof electrons (10 electrons). Hence, the given species are isoelectronic.

(b) Theionic radii of isoelectronic species increases with a decrease in themagnitudes of nuclear charge.

Thearrangement of the given species in order of their increasing nuclear charge isas follows:

N3– < O2– – < Na+ 2+ < Al3+

Nuclearcharge = +7 +8 +9 +11 +12 +13

Therefore,the arrangement of the given species in order of their increasing ionic radiiis as follows:

Al3+ < Mg2+ + < F 2– < N3–

 

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