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Question -

Calculate the entropy change in surroundingswhen 1.00 mol of H2O(l) is formed understandard conditions. ΔfHθ = –286 kJ mol–1.



Answer -

It is given that 286 kJ mol–1 of heat is evolvedon the formation of 1 mol of H2O(l). Thus, an equal amount ofheat will be absorbed by the surroundings.

qsurr = +286 kJ mol–1

Entropychange (ΔSsurr)for the surroundings = 
ΔSsurr = 959.73 J mol–1 K–1

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