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Question -

(a) Obtain the deBroglie wavelength of a neutron of kinetic energy 150 eV. As you have seen inExercise 11.31, an electron beam of this energy is suitable for crystaldiffraction experiments. Would a neutron beam of the same energy be equallysuitable? Explain. (mn= 1.675 × 10−27 kg)

(b) Obtain the deBroglie wavelength associated with thermal neutrons at room temperature (27ºC). Hence explain why a fast neutron beam needs to be thermalised with theenvironment before it can be used for neutron diffraction experiments.



Answer -

(a) DeBroglie wavelength =; neutron is not suitable for thediffraction experiment

Kinetic energy of the neutron, K =150 eV

= 150 × 1.6 × 10−19

= 2.4 × 10−17 J

Mass of a neutron, mn =1.675 × 10−27 kg

The kinetic energy of theneutron is given by the relation:

Where,

= Velocity of the neutron

mnv = Momentum of the neutron

De-Broglie wavelength ofthe neutron is given as:

It is given in the previous problem that theinter-atomic spacing of a crystal is about 1 Å, i.e., 10−10 m.Hence, the inter-atomic spacing is about a hundred times greater. Hence, aneutron beam of energy 150 eV is not suitable for diffraction experiments.

(b) De Broglie wavelength = 

Room temperature, T = 27°C= 27 + 273 = 300 K

The average kinetic energyof the neutron is given as:

Where,

k = Boltzmann constant = 1.38 × 10−23 Jmol−1 K−1

The wavelength of theneutron is given as:

Thiswavelength is comparable to the inter-atomic spacing of a crystal. Hence, thehigh-energy neutron beam should first be thermalised, before using it fordiffraction.

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