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Question -

A mercury lamp is aconvenient source for studying frequency dependence of photoelectric emission,since it gives a number of spectral lines ranging from the UV to the red end ofthe visible spectrum. In our experiment with rubidium photo-cell, the followinglines from a mercury source were used:

λ1 = 3650 Å, λ2=4047 Å, λ3= 4358 Å, λ4= 5461Å, λ5= 6907 Å,

The stopping voltages,respectively, were measured to be:

V01 = 1.28 V, V02 =0.95 V, V03 = 0.74 V, V04 =0.16 V, V05 = 0 V

Determine the value of Planck’sconstant h, the threshold frequency and work function for thematerial.

[Note: You will notice that toget from the data, you will need to know (whichyou can take to be 1.6 × 10−19 C). Experiments of this kind onNa, Li, K, etc. were performed by Millikan, who, using his own value of (fromthe oil-drop experiment) confirmed Einstein’s photoelectric equation and at thesame time gave an independent estimate of the value of h.]



Answer -

Einstein’s photoelectricequation is given as:

eV0 = − 

Where,

V0 = Stopping potential

h = Planck’s constant

e = Charge on an electron

ν = Frequency of radiation

 = Work function of amaterial

It can be concluded from equation (1) thatpotential V0 is directly proportional tofrequency ν.

Frequency is also given bythe relation:

This relation can be usedto obtain the frequencies of the various lines of the given wavelengths.

Thegiven quantities can be listed in tabular form as:

Frequency × 1014 Hz

8.219

7.412

6.884

5.493

4.343

Stopping potential V0

1.28

0.95

0.74

0.16

0

The following figure shows a graphbetween νand V0.

It can be observed that the obtained curveis a straight line. It intersects the ν-axis at 5 × 1014 Hz,which is the threshold frequency (ν0) of the material. PointD corresponds to a frequency less than the threshold frequency. Hence, there isno photoelectric emission for the λ5 line, andtherefore, no stopping voltage is required to stop the current.

Slopeof the straight line = 

From equation (1), the slope  can be written as:

The work function of themetal is given as:

hν0

= 6.573 × 10−34 × 5 × 1014

= 3.286 × 10−19 J

=2.054 eV

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