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Question -

Write the mechanism of acid-catalysed dehydration ofethanol to yield ethene.



Answer -

The mechanism of acid dehydration of ethanol to yieldethene involves the following three steps:

Step 1:

Protonation of ethanol to form ethyl oxonium ion:

Step 2:

Formation of carbocation (rate determining step):

Step 3:

Elimination of a proton to form ethene:

The acid consumed in step 1 is released in Step 3. Afterthe formation of ethene, it is removed to shift the equilibrium in a forwarddirection.

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