MENU
Question -

Illustrate with examples the limitations of Williamsonsynthesis for the preparation of certain types of ethers.



Answer -

The reaction of Williamson synthesisinvolves SN2 attack of an alkoxide ion on a primary alkyl halide.

But if secondary or tertiary alkyl halides are taken inplace of primary alkyl halides, then elimination would compete oversubstitution. As a result, alkenes would be produced. This is because alkoxidesare nucleophiles as well as strong bases. Hence, they react with alkyl halides,which results in an elimination reaction.

Comment(S)

Show all Coment

Leave a Comment

Free - Previous Years Question Papers
Any questions? Ask us!
×