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Question -

Give two reactions that show the acidic nature of phenol.Compare acidity of phenol with that of ethanol.



Answer -

The acidic nature of phenol can be represented by thefollowing two reactions:

(i) Phenolreacts with sodium to give sodium phenoxide, liberating H2.

(ii) Phenolreacts with sodium hydroxide to give sodium phenoxide and water as by-products.

The acidity of phenol is more than that of ethanol. Thisis because after losing a proton, the phenoxide ion undergoes resonance andgets stabilized whereas ethoxide ion does not.

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