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Question -

Give structures of the products you wouldexpect when each of the following alcohol reacts with (a) HCl-ZnCl2 (b)HBr and (c) SOCl2.




Answer -

(i) Butan-1-ol

(ii) 2-Methylbutan-2-ol


Answer

(a)

(i)

Primary alcohols do not react appreciablywith Lucas’ reagent (HCl-ZnCl2) at room temperature.

(ii)

Tertiary alcohols react immediately with Lucas’ reagent.

(b)

(i)

(ii)

(c)

(i)

(ii)

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