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Question -

Writethe important conditions required for the linear combination of atomic orbitalsto form molecular orbitals.



Answer -

The given conditionsshould be satisfied by atomic orbitals to form molecular orbitals:

(a) The combining atomic orbitals must havethe same or nearly the same energy. This means that in a homonuclear molecule,the 1s-atomic orbital of an atom can combine with the 1s-atomicorbital of another atom, and not with the 2s-orbital.

(b) The combining atomicorbitals must have proper orientations to ensure that the overlap is maximum.

(c)The extent of overlapping should be large.

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