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Question -

What is meant by hybridisation of atomic orbitals?Describe the shapes of spsp2sp3 hybrid orbitals.



Answer -

Hybridization is definedas an intermixing of a set of atomic orbitals of slightly different energies,thereby forming a new set of orbitals having equivalent energies and shapes.

For example, one 2s-orbitalhybridizes with two 2p-orbitals of carbon to form three new sp2 hybrid orbitals.

These hybrid orbitals haveminimum repulsion between their electron pairs and thus, are more stable.Hybridization helps indicate the geometry of the molecule.

Shape of sp hybridorbitals: sp hybridorbitals have a linear shape. They are formed by the intermixing of s and p orbitalsas:

Shape of sp2 hybrid orbitals:

sphybrid orbitals are formedas a result of the intermixing of one s-orbital and two 2p-orbitals.The hybrid orbitals are oriented in a trigonal planar arrangement as:

Shape of sp3 hybrid orbitals:

Four sp3 hybrid orbitals areformed by intermixing one s-orbital with three p-orbitals. Thefour sp3 hybrid orbitals are arranged in theform of a tetrahedron as:

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