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Question -

Definehydrogen bond. Is it weaker or stronger than the van der Waals forces?



Answer -

A hydrogen bond is definedas an attractive force acting between the hydrogen attached to anelectronegative atom of one molecule and an electronegative atom of a differentmolecule (may be of the same kind).

Due to a differencebetween electronegativities, the bond pair between hydrogen and theelectronegative atom gets drifted far away from the hydrogen atom. As a result,a hydrogen atom becomes electropositive with respect to the other atom andacquires a positive charge.

The magnitude of H-bondingis maximum in the solid state and minimum in the gaseous state.

There are two types ofH-bonds:

(i) Intermolecular H-bond e.g., HF, H2O etc.

(ii) Intramolecular H-bonde.g., o-nitrophenol

Hydrogenbonds are stronger than Van der Walls forces since hydrogen bonds are regardedas an extreme form of dipole-dipole interaction.

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