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Question -

Apart from tetrahedral geometry, anotherpossible geometry for CH4 is square planar with the four H atomsat the corners of the square and the C atom at its centre. Explain why CH4 is not squareplanar?



Answer -

Electronic configurationof carbon atom:

6C: 1s2 2s2 2p2

In the excited state, theorbital picture of carbon can be represented as:

Hence, carbon atom undergoes sp3 hybridization in CH4 molecule and takes atetrahedral shape.

For a square planar shape, the hybridizationof the central atom has to be dsp2. However, an atom ofcarbon does not have d-orbitalsto undergo dsp2 hybridization.Hence, the structure of CH4 cannot be square planar.

Moreover,with a bond angle of 90° in square planar, the stability of CH4 will be very lessbecause of the repulsion existing between the bond pairs. Hence, VSEPR theoryalso supports a tetrahedral structure for CH4.

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